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The overall separation of chemicals achieved, during distillation, depends on the following: the relative volatilities of the components, their activity coefficients, the ratio of the liquid-phase flow rate to the vapor-phase flow rate and the ratio of surface area to liquid within the distillation column.

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Common chemicals that can be overtreated include demulsifiers, corrosion inhibitors, and water clarifiers. Note that many chemicals will alter the gas/liquid surface tension and/or the viscosity of phases, which will impact separation performance.

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Liquid-liquid separators are fundamentally the same as gas-liquid separators except that they must be designed for much lower velocities. Because the difference in density between two liquids is less than between gas and liquid, separation is more difficult.

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